Thermophysical properties of binary mixtures (dimethyl carbonate + ketones) at T = (303.15, 308.15 and 313.15) K

► Thermophysical properties of dimethyl carbonate and ketones help to understand intermolecular interactions. ► Excess thermodynamic properties showed deviation from ideality. ► Empirical-semi empirical relations showed good agreement. ► Molecular size responsible for interstitial accommodation. ► Study showed significant effect of temperature on binary mixtures of dimethyl carbonate.