کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5413000 | 1506613 | 2010 | 14 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Thermophysical and sonochemical behavior of binary mixtures of hexan-1-ol with halohydrocarbons at 303.15Â K
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موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Densities and ultrasonic velocities of binary mixtures of hexan-1-ol with 1,2-dichloroethane, 1,2-dibromoethane and 1,1,2,2-tetrachloroethene have been measured over the entire range of composition at 303.15Â K at the atmospheric pressure. From these experimental data, the excess molar volumes, molar free volumes, molar isentropic compressibilities, limiting excess partial molar volumes and isentropic compressibilities; deviations in ultrasonic velocity, molecular radii, Rao's molar sound functions, parameters related to space-filling ability, Beyer's parameters of non-linearity, available volumes and intermolecular free lengths by three methods have been estimated. The excess functions have been fitted to the Redlich-Kister polynomial functions and the results have been analyzed in terms of Nomoto's relation (N), Van Dael's relation (VD), Jacobson's free length theory (FLT), Schaaffs' collision factor theory (CFT), thermoacoustical parameters (TAP) and Prigogine-Flory-Patterson theory (PFP).
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Liquids - Volume 152, Issues 1â3, 15 March 2010, Pages 39-52
Journal: Journal of Molecular Liquids - Volume 152, Issues 1â3, 15 March 2010, Pages 39-52
نویسندگان
Subhash C. Bhatia, Rachna Bhatia, Gyan P. Dubey,