کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5413063 | 1506616 | 2009 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Densities, ultrasonic speeds and excess properties of binary mixtures of methyl acrylate with 1-butanol, or 2-butanol, or 2-methyl-1-propanol, or 2-methyl-2-propanol at temperatures from 288.15 to 318.15Â K
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The densities, Ï and ultrasonic speeds, u of binary mixtures of methyl acrylate with 1-butanol, 2-butanol, 2-methyl-1-propanol, and 2-methyl-2-propanol, including those of pure liquids, over the entire composition range were measured at temperatures (288.15, 293.15, 298.15, 303.15, 308.15, 313.15, and 318.15) K and atmospheric pressure. Using the experimental data, the excess molar volume, VmE and deviations in isentropic compressibility, Îks, partial molar volumes, Vm,1°â and Vm,2°â, and excess partial molar volumes, Vm,1°E,â and Vm,2°E,â of the components at infinite dilution were calculated. The variation of these parameters with composition and temperature of the mixtures have been discussed in terms of molecular interaction in these mixtures. The values of VmE and Îks were found to be negative for all the mixtures at each temperature studied, indicating the presence of specific interactions between methyl acrylate and alkanol molecules. The negative VmE and Îks values follow the order: 1-butanol < 2-butanol < 2-methyl-1-propanol < 2-methyl-2-propanol. It is observed that the values of VmE, Îks, Vm,1°E,â and Vm,2°E,â depend upon the positions of hydroxyl and methyl groups in these alkanol molecules.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Liquids - Volume 149, Issues 1â2, 15 October 2009, Pages 9-17
Journal: Journal of Molecular Liquids - Volume 149, Issues 1â2, 15 October 2009, Pages 9-17
نویسندگان
Anil Kumar Nain, Tanu Srivastava, Jata Dhari Pandey, Swarita Gopal,