کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
5416154 1393799 2006 10 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
12C16O2 line intensity FTS measurements with 1% assumed accuracy in the 1.5-1.6 μm spectral range
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
12C16O2 line intensity FTS measurements with 1% assumed accuracy in the 1.5-1.6 μm spectral range
چکیده انگلیسی
Using Fourier-transform spectra and a multispectrum fitting procedure, 124 absolute line intensities of 12C16O2 are obtained for the cold band 30011-00001 and the hot band 01131-01101 between 6460 and 6950 cm−1. Vibrational transition dipole moments squared and Herman-Wallis coefficients are reported for each band. Cross comparisons made with previous experimental results and with data available in the HITRAN and Carbon Dioxide Spectroscopic Databank (CDSD), bring some confidence on the good level of accuracy of the present results. Motivated by the demanding needs of some atmospheric experiments dedicated to the survey of the carbon cycle, an additional evaluation of potential absolute line intensity measurement limit is also performed on recently published carbon dioxide absolute line intensity independent measurements. These are obtained in two different laboratories on the bands 30013-00001 and 30012-00001 both located in the 1.6 μm spectral window. It is shown that Fourier-transform experimental CO2 line intensity determination is approaching the challenging required figure of about 0.3% accuracy needed for the survey of the atmospheric carbon cycle.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Spectroscopy - Volume 238, Issue 1, July 2006, Pages 108-117
نویسندگان
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