کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5416210 | 1393805 | 2006 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
CO2-broadening coefficients in the ν4 + ν5 band of acetylene
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: CO2-broadening coefficients in the ν4 + ν5 band of acetylene CO2-broadening coefficients in the ν4 + ν5 band of acetylene](/preview/png/5416210.png)
چکیده انگلیسی
The CO2-broadening coefficients of 24 P- and R-branch transitions in the ν4 + ν5 band of acetylene were measured at room temperature using a diode-laser spectrometer. These lines with J values up to 26, were located in the spectral range 1270 to 1400 cmâ1. The collisional broadening coefficients were retrieved by fitting the experimental profiles to the Voigt, Rautian, and Galatry lineshape models. Two experimental values for the narrowing coefficient were determined from the spectra and compared with the theoretical narrowing coefficient. The calculations of these broadenings were also performed in the frame of a semiclassical formalism involving a simple intermolecular potential with an adjustable parameter. The theoretical results are in good agreement with the experimental results and reproduce well the J dependence of the broadening coefficients.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Spectroscopy - Volume 236, Issue 1, March 2006, Pages 52-57
Journal: Journal of Molecular Spectroscopy - Volume 236, Issue 1, March 2006, Pages 52-57
نویسندگان
Bénédicte Martin, Jacques Walrand, Ghislain Blanquet, Jean-Pierre Bouanich, Muriel Lepère,