کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5420332 | 1507492 | 2015 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Nuclear quadrupole coupling parameters and structural nature of the nonlinear optical material Li2B4O7 by NMR
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
- Two types of boron atoms.
- Quadrupole parameter.
- Principal axis of EFG tensor.
The structural nature underlying the nonlinear optical (NLO) properties of Li2B4O7 is characterized by nuclear magnetic resonance (NMR). The rotation patterns of 11B NMR were measured. We observed sixteen different spectra which were divided into two groups, corresponding to two types of boron atoms, 4-coordinated B(1) and 3-coordinated B(2), which have different boron-oxygen rings and lie at chemically inequivalent sites. From these results, the quadrupole parameter and the principal axis of the electric field gradient (EFG) tensor were determined for the two borons.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Solid State Nuclear Magnetic Resonance - Volumes 66â67, AprilâMay 2015, Pages 40-44
Journal: Solid State Nuclear Magnetic Resonance - Volumes 66â67, AprilâMay 2015, Pages 40-44
نویسندگان
Ae Ran Lim, In Gyoo Kim,