کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5420777 | 1507515 | 2008 | 4 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Improved resolution and detection of 31P-Tl J-couplings at 21Â T in 31P magic angle spinning NMR spectra of inorganic compounds containing Tl/Bi/P/S
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Improved resolution and detection of 31P-Tl J-couplings at 21Â T in 31P magic angle spinning NMR spectra of inorganic compounds containing Tl/Bi/P/S Improved resolution and detection of 31P-Tl J-couplings at 21Â T in 31P magic angle spinning NMR spectra of inorganic compounds containing Tl/Bi/P/S](/preview/png/5420777.png)
چکیده انگلیسی
For crystalline compounds containing Tl, Bi, P, and S, greatly improved chemical shift resolution was observed in 31P magic angle spinning spectra obtained at 21Â T relative to spectra obtained at 9.4Â T. In Hz units, the spectral linewidths were not strongly dependent on the applied field, which may be a result of a significant contribution to the linewidths from transverse relaxation. Comparison of the spectra at the two different fields confirmed that spectral splittings were due to two-bond phosphorus-thallium J-coupling. These results suggest that ultra-high field may be a useful tool to improve spectral resolution of spin 12 nuclei in crystalline inorganic compounds.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Solid State Nuclear Magnetic Resonance - Volume 33, Issues 1â2, JanuaryâFebruary 2008, Pages 12-15
Journal: Solid State Nuclear Magnetic Resonance - Volume 33, Issues 1â2, JanuaryâFebruary 2008, Pages 12-15
نویسندگان
Matthew A. Gave, Kermit M. Johnson, Mercouri G. Kanatzidis, David P. Weliky,