Zerovalent iron in conjunction with surfactants to remediate sediments contaminated by polychlorinated biphenyls and nickel

- A mixture of ZVI and sediment in surfactant solution is effective for PCB removal.
- The ZVI-mediated reaction was inhibited in the absence of surfactant.
- Excessive surfactant did not facilitate PCB dechlorination.
- The final degradation products partitioned mostly into the liquid phase.

Dredging and disposal is commonly used for cleanup of contaminated sediments, leaving the relocated sediments still in need of remediation. In this study, the feasibility of two approaches to using zerovalent iron (ZVI) in conjunction with surfactants to remediate sediments contaminated by polychlorinated biphenyls (PCBs) and Ni was investigated. Approach A is surfactant desorption followed by ZVI treatment and approach B is a simple mixture of ZVI and sediment in surfactant solution. Results of approach A show that 65.24% of PCBs and 2.12% of Ni were desorbed by 1% Envirosurf; however, the sequential ZVI-mediated reductive dechlorination (ZVI-RD) was ineffective due to micelle sequestration by high contents of surfactants while Ni could be almost completely removed. For approach B, less than 1% of coexisting Ni was released to aqueous solution, and 47.18%-76.31% PCBs could be dechlorinated by ZVI with the addition of 0.04% surfactants (Tween-80 and Envirosurf). Results of dechlorination kinetics and ZVI morphologies reveal that surfactants at the concentrations as low as 0.04% were able to enhance the contact of sediment-bound PCBs with ZVI, and also to alleviate ZVI passivation. The PCB mixtures in sediment were continuously desorbed and dechlorinated, yielding lower substituted homologues that are less toxic and less hydrophobic. Thus, a simple mixture of ZVI and contaminated sediments without dewatering appears to be a promising alternative to the remediation of PCBs-contaminated sediments.

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