ReviewCritical review of existing nanomaterial adsorbents to capture carbon dioxide and methane

- Novel materials and nanomaterials for CO2 and CH4 sorption are presented and compared.
- These materials have high selectivity for both gases, are easy to regenerate and cheap.
- Fe3O4-graphene and MOF-117 based NPs have reported the highest CO2 sorption capacities.
- IRMOF-6, MOF-177 and MOF-5 showed the highest adsorption capacities for CH4.
- Further studies are needed to prove their long term efficacy in real applications.

Innovative gas capture technologies with the objective to mitigate CO2 and CH4 emissions are discussed in this review. Emphasis is given on the use of nanoparticles (NP) as sorbents of CO2 and CH4, which are the two most important global warming gases. The existing NP sorption processes must overcome certain challenges before their implementation to the industrial scale. These are: i) the utilization of the concentrated gas stream generated by the capture and gas purification technologies, ii) the reduction of the effects of impurities on the operating system, iii) the scale up of the relevant materials, and iv) the retrofitting of technologies in existing facilities. Thus, an innovative design of adsorbents could possibly address those issues. Biogas purification and CH4 storage would become a new motivation for the development of new sorbent materials, such as nanomaterials. This review discusses the current state of the art on the use of novel nanomaterials as adsorbents for CO2 and CH4. The review shows that materials based on porous supports that are modified with amine or metals are currently providing the most promising results. The Fe3O4-graphene and the MOF-117 based NPs show the greatest CO2 sorption capacities, due to their high thermal stability and high porosity. Conclusively, one of the main challenges would be to decrease the cost of capture and to scale-up the technologies to minimize large-scale power plant CO2 emissions.

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