کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
5753982 | 1620717 | 2017 | 12 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Secondary organic aerosol formation from ethylene ozonolysis in the presence of sodium chloride
ترجمه فارسی عنوان
تشکیل آئروسل های آلی متوسط از اسیلنز اتیلن در حضور کلرید سدیم
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کلمات کلیدی
اوزنولیز اتیلن، آرسنیک آلی متوسط، سدیم کلرید، رطوبت نسبی،
موضوعات مرتبط
مهندسی و علوم پایه
علوم زمین و سیارات
علم هواشناسی
چکیده انگلیسی
Secondary organic aerosol (SOA) formation from the gas-phase ozonolysis of ethylene without irradiation was studied at different levels of relative humidity (RH) in both absence and presence of sodium chloride (NaCl) in a Teflon bag reactor. Results show that a small amount of SOA was formed from the ethylene ozonolysis in the absence of NaCl. When NaCl was in the form of liquid droplets, much more SOA could be formed. With the initial concentrations of 1 ppm and 0.5 ppm for ethylene and ozone, SOA concentrations of 3.0 to 8.6 μg/m3 were obtained after 5-h reactions under RH levels of 62% to 88% in the presence of NaCl seed particles, which were about 3~9 times higher than the results from the experiments without NaCl. The yield of SOA also increased with increasing RH, with the value being 3.0% at 88% RH in the presence of NaCl. Addition of the scavenger of OH radicals (n-hexane, ~900 ppm) into the reaction system at 86% RH resulted in a decrease of the SOA yield by 21%. The liquid water content in aerosols was a key factor to SOA formation in the presence of different seed particles, including NaCl and Na2SO4. An analysis of the SOA with a Fourier-transform (FT) IR spectrometer shows that the particles formed from the ethylene ozonolysis were organic compounds that contained the functional groups of O-H, C=O, C-O, C-Cl and C-OH. The heterogeneous aqueous reaction is probably an effective pathway to form SOA from the ethylene ozonolysis, which should be considered in the atmosphere.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Aerosol Science - Volume 106, April 2017, Pages 120-131
Journal: Journal of Aerosol Science - Volume 106, April 2017, Pages 120-131
نویسندگان
Shuangshuang Ge, Yongfu Xu, Long Jia,