کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
577221 | 1453097 | 2013 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Perchlorate reduction by the sulfite/ultraviolet light advanced reduction process
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
بهداشت و امنیت شیمی
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چکیده انگلیسی
Advanced reduction processes (ARPs) are a new class of water treatment processes that combine activation methods and reducing agents to form highly reactive reducing radicals that degrade oxidized contaminants. The combination of sulfite with low-pressure ultraviolet light (UV-L) is the most effective ARP tested to date. In this study, batch kinetic experiments were conducted to characterize the kinetics of perchlorate destruction by the sulfite/UV-L ARP. Experimental variables were pH, sulfite concentration, temperature and UV-L irradiance. The rate of perchlorate degradation by sulfite/UV-L increases with increasing pH and temperature and increases with increasing sulfite concentration to a maximum and then decreases due to lack of mixing within the reactor system used. Efficiency of perchlorate degradation was measured as a quantum yield and was observed to decrease with increasing sulfite concentration. The ultimate product of perchlorate degradation by the sulfite/UV-L ARP is chloride, but chlorate was detected as an intermediate.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Hazardous Materials - Volume 262, 15 November 2013, Pages 348-356
Journal: Journal of Hazardous Materials - Volume 262, 15 November 2013, Pages 348-356
نویسندگان
Bhanu Prakash Vellanki, Bill Batchelor,