کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
596156 1454033 2009 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Single-component and competitive adsorption of levulinic/formic acids on basic polymeric adsorbents
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی شیمی کلوئیدی و سطحی
پیش نمایش صفحه اول مقاله
Single-component and competitive adsorption of levulinic/formic acids on basic polymeric adsorbents
چکیده انگلیسی

The adsorption equilibria of single-component and binary mixtures of levulinic/formic acids in the aqueous solution on three different types of basic polymeric adsorbents were experimentally measured at 30 °C. Adsorption isotherms such as Langmuir, Freundlich and Sips were applied to correlate the single-solute adsorption data. Results demonstrated that the adsorption isotherms of both acids on all three adsorbents were best described by the Sips model, and that formic acid has higher adsorption capacity and stronger affinity on all three resins. The adsorption of binary mixtures of formic/levulinic acids reveals that formic acid is preferentially adsorbed and levulinic acid can be competitively displaced by formic acid. Binary Sips model and the ideal adsorbed solution (IAS) theory were employed to simulate the binary competitive adsorption data. The binary Sips model cannot predict the competitive adsorption behavior. The IAS model was successfully coupled with Sips isotherm parameters determined from single-component adsorption data to predict the binary competitive adsorption behavior of levulinic/formic acids on all three resins.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Colloids and Surfaces A: Physicochemical and Engineering Aspects - Volume 339, Issues 1–3, 1 May 2009, Pages 185–191
نویسندگان
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