کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
597918 1454081 2006 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Formation of uniform colloidal ceria in polyol
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی شیمی کلوئیدی و سطحی
پیش نمایش صفحه اول مقاله
Formation of uniform colloidal ceria in polyol
چکیده انگلیسی

Well-dispersed uniform spheres of crystalline CeO2 were prepared by calcining precursor particles obtained by heating cerium(III) acetate in 1,2 propane diol (propylene glycol, PG) at the boiling point of the polyol (∼187 °C) for several hours. The first precipitated amorphous spherical particles consist of a complex mixture of ceria, ceria hydrate, cerium hydroxide, cerium glycolate complex and residual PG. To convert these precursors to pure CeO2, the solids were calcined at 500 °C in air at a slow heating rate (≤0.1 °C/min). The purification of the precursor particles depended strongly on the solvent used. By washing with water, much of the organic material was leached out resulting in smaller spheres, while rinsing with methanol showed little effect. The TGA, FTIR, XRD, EDX analyses of the different purified particles revealed the stages in the formation of the final pure well-defined CeO2 powder.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Colloids and Surfaces A: Physicochemical and Engineering Aspects - Volume 291, Issues 1–3, 15 December 2006, Pages 93–100
نویسندگان
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