Formation and characterization of shellac-hydroxypropyl methylcellulose composite films

Shellac-hydroxypropyl methylcellulose composite films (Sh-HPMC-CFs) were produced and the effects of emulsifier and shellac concentration on the Sh-HPMC-CFs were investigated. Two emulsifiers, stearic acid (SA) and lauric acid (LA), with three ratios of shellac to emulsifier (100:1, 20:1, and 10:1) were tested to select the best ratio of shellac to emulsifier before testing the effect of shellac concentration. When compared to pure HPMC film, the WVP was decreased by 6 and 11% in the Sh-HPMC-CFs containing shellac to LA (ShLA) ratios of 100:1 and 20:1, respectively. However, all the ShSA-HPMC-CFs had higher WVP than the pure HPMC film. In relation to mechanical properties, the ShLA(20:1)-HPMC-CF had the lowest reduction in TS when compared to a pure HPMC film. Therefore, ShLA(20:1) was selected for further characterization. Surface morphology, cross sectional image, thermal stability, WVP, and mechanical properties of the Sh-HPMC-CFs were also measured at varying shellac concentrations (0.1, 0.5, 1.0, and 1.5%). The 0.1 and 0.5% Sh-HPMC-CFs had good distribution of shellac in the film structure while the 1.0 and 1.5% Sh-HPMC-CFs exhibited some agglomeration of shellac. The 0.1 and 0.5% Sh-HPMC-CFs had better moisture barrier than the pure HPMC film. All Sh-HPMC-CFs had better thermal stability than the pure HPMC film and its thermal stability increased as shellac concentration increased.

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► Shellac-hydroxypropyl methylcellulose composite films (Sh-HPMC-CFs) were produced.
► Lauric acid had better emulsifier than stearic acid.
► 0.1% Sh-HPMC-CF had smooth surface and well dispersion of shellac.
► 0.1% Sh-HPMC-CF had the best barrier property.