کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6309978 | 1618877 | 2014 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
The release of persistent organic pollutants from a closed system dicofol production process
ترجمه فارسی عنوان
انتشار آلاینده های آلی پایدار از فرایند تولید دیسیفول سیستم بسته
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موضوعات مرتبط
علوم زیستی و بیوفناوری
علوم محیط زیست
شیمی زیست محیطی
چکیده انگلیسی
High concentrations of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) have been found to be produced in chemical processes in which chlorine is a raw material. Samples of workshop air, waste water, waste acid, and the dicofol product were collected from a pesticide factory in China that uses a closed-system dicofol production process, and were analyzed for PCDD/Fs and ΣDDTs. The ΣDDTs concentrations were 1.88-17.53 μg mâ3 in the workshop air samples, 4.85-456 μg kgâ1 in the waste water and waste acid samples, and 4.74 g kgâ1 in the dicofol product. The total estimated daily intakes of ΣDDTs for workers by inhalation in the workplace were in the range of 0.38-3.51 μg kgâ1 bw dâ1 for moderate activities. The annual amounts of ΣDDTs and p,pâ²-DDT directly released to the environment via the use of dicofol were 9480 kg and 1080 kg, respectively. The PCDD/F toxicity equivalent values (I-TEQs) in the waste water and waste acid samples ranged from 1.5 to 122 pg I-TEQ kgâ1 and 86.3 ng I-TEQ kgâ1 in the dicofol sample. The annual amount of PCDD/Fs released to the environment was 0.17 g I-TEQ. From the PCDD/F distribution patterns, it is suggested that the major pathway for PCDD/F formation involves precursor synthesis during the production of dicofol in the closed-system process.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemosphere - Volume 94, January 2014, Pages 164-168
Journal: Chemosphere - Volume 94, January 2014, Pages 164-168
نویسندگان
Sumei Li, Yajing Tian, Qiong Ding, Wenbin Liu,