Hazardous organic chemicals in rubber recycled tire playgrounds and pavers

► A large number of recycled tire playgrounds and commercial pavers have been analysed. ► The occurrence of numerous harmful compounds at high levels was confirmed. ► Thirty-one targets (PAHs, vulcanisation additives, antioxidants, plasticizers) were selected. ► Total PAH concentration was remarkable. Contribution of B[a]P must be highlighted. ► Target analytes were detected in the headspace SPME experiments at room temperature.