Preparation, characterization and gas permeation properties of polyurethane–silica/polyvinyl alcohol mixed matrix membranes

Silicon based particles were synthesized by using tetraethoxysilane (TEOS) as silica precursor, and low concentration of cetyltrimethyl ammonium bromide (CTAB) with polyvinyl alcohol (PVA) as templating agents. The synthesized particles had a higher hydrophilicity and polarity than conventional silica particles. PU and PU/silica composite membranes were prepared by solution casting technique. Hybrid membranes were characterized using Fourier transform infrared spectroscopy (FT-IR), scanning electron microscope (SEM), thermal gravimetric analysis (TGA) and differential scanning calorimetery (DSC). FT-IR result indicated the existence of PVA in the final structure of silica network. The SEM micrographs confirmed the nano-scale distribution of silica particles in the polymer matrix. Gas permeation properties of membranes with different silica contents, was studied for pure CO2, CH4, O2 and N2 gases. The results showed an increase in the solubility and a corresponding reduction in the diffusivity of the gases through the membranes by increasing the silica content in the polymer matrix; consequently, the permeability of the condensable and polar CO2 gas was enhanced whereas that of other gases decreased. In the membrane with 10 wt% silica content an enhancement of CO2/CH4 (α≈10.1) and CO2/N2 (α≈70.7) selectivities was observed. Finally, the experimental permeability values were compared with theoretical predictions based on gas solubility and diffusivity.

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► Silica particles have been synthesized in presence of PVA using in situ method.
► The particles had higher polarity compared to the conventional silica particles.
► We have utilized these particles in PU matrix to prepare mixed matrix membranes.
► The results of permeability tests confirmed high CO2 permeability, up to 50 Barrer.
► The membranes have shown high selectivity (CO2/N2: 71).