کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
6452416 1417592 2017 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Short noteEmission properties of diazines chromophores: Structure-properties relationship
ترجمه فارسی عنوان
خواص نهایی خواص کروموفورهای دیازین: ساختار-خواص رابطه
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی بیو مهندسی (مهندسی زیستی)
چکیده انگلیسی


- The photophysical properties of diazine chromophores have been studied.
- The influence of five parameters has been studied by Taguchi methodology.
- ANOVA method permits to highlight the influence of each parameter.

This article presents the photophysical properties of a series of diazine chromophores. The influence of five parameters has been studied: the presence of a diazine/benzodiazine fragment, the nature of the diazine fragment (1,3-diazine/1,4-diazine), the presence or not of an vinyl linker between diazine ring and phenylene fragments of the π-conjugated bridge, the presence of a phenylene/biphenylene linker and the nature of electron donating group (dimethylamino/diphenylamino). Taguchi's design of experiment combined with analysis of variance methodologies have been employed to highlight the main structural parameters influencing the position of absorption and emission maxima of dichloromethane solution and the extend of emission solvatochromic range exhibited by this family of chromophores.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Photochemistry and Photobiology A: Chemistry - Volume 348, 1 November 2017, Pages 281-286
نویسندگان
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