Sequential two-step hydrothermal growth of MoS2/CdS core-shell heterojunctions for efficient visible light-driven photocatalytic H2 evolution

- MoS2/CdS core-shell catalyst were prepared through a “sequential two-step hydrothermal growth” route.
- The MoS2/CdS composites could act as Pt-free photocatalyst for high-efficient PHE.
- The micro-structure of catalyst could be easily tuned.
- The mechanism for enhanced PHE activity was elucidated.

The visible-light driven, Pt-free photocatalytic H2 evolution (PHE) is promising for clean and sustainable H2 production. The construction of the heterojunction structure with intimate contact and good light adsorption ability is important for realizing the high effective PHE. Here, the core-shell structured MoS2/CdS hybrids were constructed through “sequential two-step hydrothermal growth” route for Pt-free PHE. In the synthesis, the hierarchical flower-like MoS2 was firstly obtained through the reaction of ammonium molybdate and excessive thiourea. Subsequently, without need of centrifugation, the cadmium acetate (Cd source) was added into the cooled MoS2 solution directly followed by a secondary hydrothermal reaction. In the process, the Cd2+ could react with partially S2− in MoS2 (substituted reaction) and with the excessive S2− ions in solution to generate CdS, resulting in the formation of CdS shell contacted with MoS2 core. The micro-structure of the composites (such as the thickness and morphology of CdS shell) could be tuned by changing the amount of Mo source and Cd source. In the composites, the CdS on the outside is convenient to absorb the solar light. The intimate contact of CdS and MoS2 is beneficial to charge transfer. As a result, the MoS2/CdS catalyst showed high catalytic activity for PHE under visible light irradiation (λ > 420 nm). The H2 evolution rate could reach to 775 μmol h−1 (20 mg catalyst), which is much higher than pure CdS (12 μmol h−1) and Pt-CdS (64 μmol h−1). The good activity should be related with CdS outside shell beneficial for light adsorption and intimate contact of CdS and MoS2 for easy charge transfer. A series of experiments demonstrate that the formation of the heterojunction can effectively enhance the charge transfer ability and retard the recombination of electron-hole pairs, thus improving PHE activity and alleviating the photocorrosion of CdS component.

A easy and effective “sequential two-step hydrothermal growth” route has been developed for the construction of the core-shell structured MoS2/CdS hybrids with tunable micro-structure. The MoS2/CdS photocatalyst showed high catalytic activity (775 μmol h−1) and improved stability for PHE under visible light irradiation (λ > 420 nm).95