کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
6472304 1424137 2016 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Regulation of Microstructure and Composition of Cobalt Selenide Counter Electrode by Electrochemical Atomic Layer Deposition for High Performance Dye-Sensitized Solar Cells
ترجمه فارسی عنوان
تنظیم میکروارگانیسم و ​​ترکیب الکترودهای شمسی سلنید کبالت توسط رسوب لایه اتمی الکتروشیمیایی برای سلول های خورشیدی حساس به نور با کارایی بالا
کلمات کلیدی
سلناید کبالت، شمارنده الکترود، رسوب تحت فشار، رسوب لایه اتمی الکتروشیمیایی، بازده عکسبرداری،
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
چکیده انگلیسی

By means of electrochemical atomic layer deposition (ECALD), cobalt selenide counter electrodes have been successfully prepared on FTO substrate for the first time. The as-grown films presented amorphous structure and their composition and microstructure could be regulated effectively by adjusting the depositing potential of Se via the route of ECALD. Cycle voltammograms and Tafel polarization measurements revealed that the cobalt selenide counter electrode exhibited an excellent catalytic activity and stability in the I−/I3− system. Due to the more active catalytic sites and less charge-transfer resistance, the Co1.2Se counter electrode yielded faster and more complete reduction of I3− to I− than the Pt and other compositions of cobalt selenide. As a result, the dye-sensitized solar cell based on the Co1.2Se counter electrode yielded a photoconversion efficiency of 9.28%, which improved by 136% than that of the DSSC based on the Pt electrode (6.84%). Taking the facility and cost efficiency into consideration, ECALD has great potential in preparing high efficient counter electrode for high performance DSSCs.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 220, 1 December 2016, Pages 169-175
نویسندگان
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