کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
6472387 1424137 2016 12 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Expansion of titanate nanotubes by the use of a surfactant and its improved performance as an anode in Li-ion batteries
ترجمه فارسی عنوان
گسترش نانولوله های تیتانات با استفاده از سورفاکتانت و عملکرد آن به عنوان یک آند در باتری های لیتیوم یون
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
چکیده انگلیسی

The tubular and layered structure of titanate nanotubes facilitate ion movement and provide a high rate capability. Moreover, expansion of the material can enhance its performance. In this study, regular titanate nanotubes and expanded titanate nanotubes were synthesized. To expand the nanotubes, dodecylamine were used under hydrothermal conditions. SEM, TEM, BET, and XRD were utilized to characterize these materials. In addition to that, electrochemical characterizations like cyclic voltammetry, rate capability, and cycle stability tests were made to understand the effect of titanate expansion on Li-ion electrode performance. After the expansion, the d-spacing increased from 8.1 Å to 9.5 Å and parallel to that, the specific surface area reached to 297 m2 g−1 from 204 m2 g−1. Cyclic voltammograms had broad peaks and suggested a pseudocapacitive character; which is common for titanate nanotubes. Sloping potential-capacity profiles also supported this character. The first discharge capacity of regular nanotubes was 823 mAh g−1. However, after the expansion, it increased to 1017 mAh g−1. Above all, both of the nanotubes had superior rate capabilities and stabilities due to their high aspect ratios. Moreover, dodecylamine created a protective layer on the titanate surface and enhanced the stability. Finally, it was realized that the expansion of the structure is crucial and enhances the electrode performance.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 220, 1 December 2016, Pages 453-464
نویسندگان
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