کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6472453 | 1424137 | 2016 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
High-performance Transparent and Flexible Asymmetric Supercapacitor based on Graphene-wrapped Amorphous FeOOH Nanowire and Co(OH)2 Nanosheet Transparent Films Produced at air-water interface
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: High-performance Transparent and Flexible Asymmetric Supercapacitor based on Graphene-wrapped Amorphous FeOOH Nanowire and Co(OH)2 Nanosheet Transparent Films Produced at air-water interface High-performance Transparent and Flexible Asymmetric Supercapacitor based on Graphene-wrapped Amorphous FeOOH Nanowire and Co(OH)2 Nanosheet Transparent Films Produced at air-water interface](/preview/png/6472453.png)
چکیده انگلیسی
The preparation of high specific-capacity pseudocapacitive transition-metal-oxide/hydroxide (TMH) materials into transparent micro-structure electrodes is a great challenge and has become the bottleneck restricting the performance of transparent flexible supercapacitors. Beyond that, extending the operating voltage window is an urgent need for improving energy density. Here, Co(OH)2 nanosheets and amorphous FeOOH nanowires were prepared into transparent films through a simple and scalable bio-inspired method at the air-solution interface. Both nanostructures are enwrapped in graphene shells (Co@Gr-TFandFe@Gr-TF) for use as transparent asymmetric pseudocapacitive electrodes. The unique encapsulation structures (1) provide pseudocapacitive electrode materials, especially an amorphous FeOOH structure cathode, (2) build up rapid three-dimensional electron and ion transport pathways together with the underlying ITO layer, (3) alleviate the exfoliation and dissolution of the active materials into electrolyte, and (4) extend the potential window of the FeOOH cathode from â0.8 â¼Â 0 V to â1.2 â¼Â 0 V with minimal cycling stability degradation. The asymmetric transparent and flexible supercapacitor based on Co@Gr-TF//Fe@Gr-TF operated at 1.8 V exhibits good transparency (50.5% at 550 nm), high specific capacitance (25.5 mF cmâ2, one order higher than the maximum value reported for FFT-GP), and high energy density (1.04 mWh cmâ3, comparable to that of nontransparent devices) as well as a long cycle life (10 000 cycles) with high-capacity retention (83.5%).
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 220, 1 December 2016, Pages 618-627
Journal: Electrochimica Acta - Volume 220, 1 December 2016, Pages 618-627
نویسندگان
Na Li, ChunYi Zhi, Haiyan Zhang,