کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6477388 | 1362584 | 2017 | 11 صفحه PDF | دانلود رایگان |
- Hetero-catalytic wet oxidation of a mixture of phenolics was performed.
- 5%Cu/AC catalyst was synthesized and detailed characterization was conducted.
- Non-oxidative hydrothermal treatment was also investigated.
- Performance of homo-catalytic reaction using Cu2+ was also studied.
- Copper leaching was measured with time during wet oxidation process.
The present study investigated the efficiency of catalytic wet oxidation (CWO) for the destruction of three phenolic compounds (phenol, o-cresol and 2,5-dimethylphenol) individually as well as in mixture (phenolics concentration = 10 g/L, NaOH concentration = 10 g/L, chemical oxygen demand (COD) = 24000 mg/L, total organic carbon (TOC) = â¼7800 mg/L and pH â¼13). The oxidative hydrothermal reaction was carried out in a laboratory scale high pressure batch reactor (capacity = 0.7 L) at moderate temperature (120-160 °C) and pressure (oxygen partial pressure = 0.8 MPa) conditions in the presence of a heterogeneous catalyst (i.e., 5% Cu/activated carbon). After 4 h CWO reaction on the mixture of phenolics at a reaction temperature of 160 °C and initial reaction pH of 9.0, TOC and COD were reduced by â¼90% and 82%, respectively. The phenolics removal was mainly due to the oxidation reaction and the contribution of other reactions such as adsorption and/or hydrolysis was lower. The copper leaching in the solution was found to be 15-26 ppm. The characterization of recovered catalyst showed increase in carbon content thus confirming the deposition of carbonaceous deposit.
Journal: Journal of Environmental Chemical Engineering - Volume 5, Issue 1, February 2017, Pages 468-478