کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
65777 48403 2013 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis, characterization and investigation of homogeneous oxidation activities of peripherally tetra-substituted Co(II) and Fe(II) phthalocyanines: Oxidation of cyclohexene
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Synthesis, characterization and investigation of homogeneous oxidation activities of peripherally tetra-substituted Co(II) and Fe(II) phthalocyanines: Oxidation of cyclohexene
چکیده انگلیسی


• Synthesis and characterization of peripherally tetra-substituted cobalt and iron phthalocyanines.
• Investigation of catalytic activity of cobalt and iron phthalocyanine in cyclohexene oxidation.
• Determination of substrate, oxidant and temperature effect on cyclohexene oxidation.

The synthesis and characterization of novel peripherally tetra-substituted iron(II) 4 and cobalt(II) 5 phthalocyanines are described for the first time in this study. All the new compounds are characterized by a combination of IR, 1H and 13C NMR, mass and UV–vis spectroscopy techniques. Complexes 4 and 5 served as catalyst for the oxidation of cyclohexene using different types of oxidants, such as tert-butyl hydroperoxide (TBHP), m-chloroperoxybenzoic acid (m-CPBA), aerobic oxygen and hydrogen peroxide (H2O2). During the oxidation process the products formed are 2-cyclohexene-1-ol, 2-cyclohexene-1-one and cyclohexene oxide. The selectivity for 2-cyclohexene-1-ol is favored when iron(II) and cobalt(II) phthalocyanine catalysts are employed. The higher conversion is obtained as catalyst iron(II) phthalocyanine (96%). TBHP was determined as the successful oxidant with the minimum demolition of the catalyst, superior selectivity and conversion in the oxidation products.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Molecular Catalysis A: Chemical - Volume 378, 1 November 2013, Pages 156–163
نویسندگان
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