کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6585839 | 456382 | 2015 | 23 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Effective and reusable oil/water separation membranes based on modified polysulfone electrospun nanofiber mats
ترجمه فارسی عنوان
غشاء جداسازی روغن / آب موثر و قابل استفاده مجدد بر پایه پلی کربنات پلی ساوفون پلی کربنات نانوفیبری
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
چکیده انگلیسی
Membrane technology is the most promising process for oil/water separation operation if the hydrophilicity, fouling and reusability properties could be improved. In this study, novel effective and reusable membrane for oil-water separation process is introduced based on modification of polysulfone (PSF) electrospun nanofiber mats. The modification process was achieved by incorporation of NaOH nanoparticles inside the PSF nanofibers, and formation of a thin layer from a polyamide polymer on the surface of the electrospun mat. Typically, solutions composed of PSF and NaOH (twelve solutions were prepared based on different PSF concentrations; 15, 18 and 20 wt%, and various NaOH content; 1.5, 1.7 and 2.5 wt%) have been electrospun, then the dried nanofiber mats were treated by m-phenylenediamine and 1,3,5-benzenetricarbonyl chloride to form polyamide thin layer on the surface of the mats. The results indicated that incorporation of NaOH and the formed polyamide could decrease the water contact angle from â¼130° to 13° for the nanofiber mats obtained from 20 wt% PSF solutions containing 1.7 wt% sodium hydroxide. Interestingly, the membrane having the lowest contact angle could separate oil-water mixture for three successive cycles with complete removal of the oil at a relatively high water flux; 5.5 m3/m2 day. Overall, simplicity of the manufacturing technique, and effectiveness and reusability of the produced nanofiber mats open new avenue for the introduced electrospun mats as promising membranes for the oil-water separation process.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Engineering Journal - Volume 259, 1 January 2015, Pages 449-456
Journal: Chemical Engineering Journal - Volume 259, 1 January 2015, Pages 449-456
نویسندگان
M. Obaid, Nasser A.M. Barakat, O.A. Fadali, Moaaed Motlak, Abdulhakim A. Almajid, Khalil Abdelrazek Khalil,