کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6601860 | 1424073 | 2018 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Nanocomposites CoPt-x/Diatomite-C as oxygen reversible electrocatalysts for zinc-air batteries: Diatomite boosted the catalytic activity and durability
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The exploration of oxygen reversible electrocatalysts to boost oxygen reduction reaction and oxygen evolution reaction is critical for the development of high-performance aqueous Zn-air batteries. Since diatomite with porous structure can adsorb metal ions in aqueous solution, herein, we prepare the nanocomposite CoPt-x/Diatomite-C for both oxygen reduction and evolution reactions, and diatomite is found significantly promotes the electrocatalytic activity and durability. With the presence of diatomite, CoPt-1/Diatomite-C shows a lower Tafel slope (63â¯mV decâ1 at high potential range), larger diffusion-limited current density (4.94â¯mAâ¯cmâ2) and superior durability for ORR. Particularly, the specific and mass activities of CoPt-1/Diatomite-C for ORR are 0.74â¯mAâ¯cmâ2 and 286â¯mAâ¯mgâ1, respectively, which are 2.5 and 3.0 times higher than that of CoPt-1/C without diatomite; For OER, the overpotential of CoPt-9/Diatomite-C decreases nearly 30â¯mVâ¯at 10â¯mAâ¯cmâ2, while the Tafel slope also reduces 16â¯mV decâ1 versus CoPt-9/C catalyst. Moreover, a rechargeable Zn-air battery with these composites as air-cathode is self-assembled, and diatomite boosts the battery performance with desirable properties. CoPt-9/Diatomite-C displays the optimal performance, with a power density of 140â¯mWâ¯cmâ2, a specific capacity of 616â¯mAâ¯hâ¯gâ1 at 10â¯mAâ¯cmâ2 and an exceedingly robust cycling life. This work provides a viable and cost-effective strategy for fabricating oxygen reversible electrocatalysts for metal-air battery applications.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 284, 10 September 2018, Pages 119-127
Journal: Electrochimica Acta - Volume 284, 10 September 2018, Pages 119-127
نویسندگان
Kai Wang, Zhenghua Tang, Wen Wu, Pinxian Xi, Dong Liu, Zhaoqing Ding, Xiaoning Chen, Xiao Wu, Shaowei Chen,