کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6602919 | 1424082 | 2018 | 50 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Copper metal-organic framework-derived CuOx-coated three-dimensional reduced graphene oxide and polyaniline composite: Excellent candidate free-standing electrodes for high-performance supercapacitors
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
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چکیده انگلیسی
A novel multicomponent hybrid of copper metal-organic framework (MOF)-derived copper oxide@mesoporous carbon (CuOx@mC) embedded with polyaniline (PANI) and reduced graphene oxide (rGO) was synthesized by in-situ polymerization (denoted as CuOx@mC@PANI@rGO). After detailed characterizations of basic chemical and physical performances, the series of as-prepared CuOx@mC@PANI@rGO composites were explored as electrode materials for supercapacitors. Results demonstrated that a uniformly and highly ordered interface layer of PANI together with rGO nanosheets was formed on the surface of the CuOx@mC frameworks because of the regular octahedral structure of CuOx@mC composite. This efficient conductive network can enhance the ion-diffusion process and fast redox reaction at the electrode/electrolyte interface, leading to increased electrical conductivity and enhanced capacitive performance. By changing the pyrolysis temperature of Cu-MOF, the ternary CuOx@mC@PANI@rGO obtained at 700â¯Â°C exhibited the highest capacitance of up to 534.5â¯Fâ¯gâ1 and outstanding cycling stability. Conversely, the corresponding CuOx@mC@PANI showed only a specific capacitance of 456.0â¯Fâ¯g-1â¯at a discharge current density of 1â¯Aâ¯gâ1. These findings may broaden the applications of metal-organic framework-derived composites as high-performance supercapacitors.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 275, 10 June 2018, Pages 133-144
Journal: Electrochimica Acta - Volume 275, 10 June 2018, Pages 133-144
نویسندگان
Linghao He, Jiameng Liu, Longyu Yang, Yingpan Song, Minghua Wang, Donglai Peng, Zhihong Zhang, Shaoming Fang,