کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6602966 | 1424083 | 2018 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Porphyrin-stabilized CNT in nanofiber via non-covalent interaction for enhanced electrochemical performance
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Herein, a new fabrication method for CNT nanofiber composite (pPC-FP) through non-covalent interaction between porphyrin monomers with CNTs is reported. This led to the alleviated agglomeration of pristine CNT without acid pre-treatment, producing a highly porous material with high surface area of 444â¯m2/g and narrow pore size distribution for all pPC-FP nanofiber composites. Enhanced performances of pPC-FP3 and pPC-FP5 (CNT nanofiber with porphyrin monomers) were brought about by the enhanced CNT dispersion, hence, better porosity as compared to pPC. Moreover, through the incorporation of porphyrin monomer, M-NC bond was simultaneously formed and served as a contributor to the excellent capacitive performance of the material, resulting in the highest capacitance of 150 A/cm2 at 0.25â¯mAh/cm2 with 77 A/cm2 at 2.5â¯mAh/cm2. The composites also exhibited stable performance even after cycling at different current densities (0.25-2.5â¯mAh/cm2) for 3000 cycles with almost 100% columbic efficiency. Through Ï-Ï stacking interaction, the agglomeration was prevented and CNT was aligned along the axis of the polymer which rendered the nanofibers highly porous resulting to a conductive composite material with excellent electrochemical performance.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 274, 1 June 2018, Pages 112-120
Journal: Electrochimica Acta - Volume 274, 1 June 2018, Pages 112-120
نویسندگان
Alan Christian Lim, Hyuk Jae Kwon, Harsharaj S. Jadhav, Jeong Gil Seo,