کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
6605314 1424100 2017 34 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Electrochemistry and spectroelectrochemistry of polymers based on D-A-D and D-D-D bis(N-carbazolyl) monomers, effect of the donor/acceptor core on their properties
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Electrochemistry and spectroelectrochemistry of polymers based on D-A-D and D-D-D bis(N-carbazolyl) monomers, effect of the donor/acceptor core on their properties
چکیده انگلیسی
In this work we present electropolymerization of monomers of an unusual type using N-linked carbazole units to limit their conjugation. The polymers thus obtained have limited conjugation through the backbone. Using donor-acceptor-donor (D-A-D) and donor-donor-donor (D-D-D) monomers we evaluate the effects of the presence (or absence) of charge transfer states on synthesized electropolymers. The use of a D-A-D monomer resulted in obtaining an ambipolar polymer with quasi-reversible reduction.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 257, 10 December 2017, Pages 192-202
نویسندگان
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