کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6606187 | 459523 | 2016 | 33 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Nitrogen and Oxygen-Doped Hierarchical Porous Carbons from Algae Biomass: Direct Carbonization and Excellent Electrochemical Properties
ترجمه فارسی عنوان
کربن های متخلخل سلولز نیتروژن و اکسیژن دوگانه از زیست توده جلبک: کربنیزاسیون مستقیم و خواص الکتروشیمیایی عالی
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
چکیده انگلیسی
Herein, the algae pollutants of Enteromorpha prolifera were applied as precursors to obtain nitrogen and oxygen co-doped hierarchical carbons with major pores at around 1.5 and 5.0 nm through direct carbonization at 700 and 900 °C after freeze-drying treatment. Physical properties of porous carbons including morphology, elemental analysis, and pore size distribution were evaluate by transmission electron microscopy, X-ray photoelectron spectroscopy and N2 sorption. In both cases, surface areas were only close to 450 m2 gâ1 with 70% areas inherited from mesopores, resulting in high density materials. The carbon derived at 700 °C had the highest capacitance of 234 F gâ1 at a current density of 0.5 A gâ1 in 6 M KOH electrolyte and also had excellent cycling stability with 95% of capacitance after 2000 cycles, owing to the naturally heteroatoms and unique hierarchical nanopores contributed pseudo-capacitance and provided active sites for facilitating electrolyte ions diffusion. In addition, the carbon derived at 900 °C had CO2 uptake of 6.48 mmol gâ1 at 20 bar and 25 °C.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 211, 1 September 2016, Pages 225-233
Journal: Electrochimica Acta - Volume 211, 1 September 2016, Pages 225-233
نویسندگان
Zhongwei Tian, Min Xiang, Jicheng Zhou, Langqing Hu, Jinjun Cai,