کد مقاله کد نشریه سال انتشار مقاله انگلیسی ترجمه فارسی نسخه تمام متن
6607245 459532 2016 9 صفحه PDF سفارش دهید دانلود رایگان
عنوان انگلیسی مقاله ISI
Nanoplate and mulberry-like porous shape of CuO as anode materials for secondary lithium ion battery
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موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Nanoplate and mulberry-like porous shape of CuO as anode materials for secondary lithium ion battery
چکیده انگلیسی
Facile hydrothermal synthesis of nanoplate and mulberry-like porous shape of CuO nanostructures was developed as anode materials for application in lithium ion batteries. The powder X-ray diffraction patterns of both the samples were indexed well to a pure monoclinic phase of CuO with no impurities. The CuO sample synthesized at different pH and reaction temperature exhibited nanoplate with average width and length of ∼150-300 nm and ∼300-700 nm and mulberry-like porous shape of CuO with average length of ∼300-400 nm. Electrochemical tests show that the lithium storage performances of both the nanoplate and mulberry-like samples are influenced more closely to its structural aspects than their morphology and size factors. The CuO nanoplate electrode exhibits high reversible charge capacity of 279.3 mAh g−1 at 1.0C after 70 cycles, and a capacity of 150.2 mAh g−1 even at high current rate of 4.0C during rate test, whereas the mulberry-like porous shape of CuO anode delivers only 131.4 mAh g−1 at 1.0C after 70 cycles and 121.7 mAh g−1 at 4.0C. It is believed that the nanoplate type architecture is very favorable to accommodate the volume expansion/contraction and aggregation of particles during the cyclic process. In contrast, the mulberry-like porous morphology could not preserve the integrity of the structure and completely disintegrated into nanoparticles during Li+ ion insertion/deinsertion due to the loose contact between the particles.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 206, 10 July 2016, Pages 217-225
نویسندگان
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