کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6608474 | 459541 | 2016 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
A study of the charge storage properties of a MoSe2 nanoplatelets/SWCNTs electrode in a Li-ion based electrolyte
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
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چکیده انگلیسی
MoSe2 nanoplatelets were synthesised by liquid phase exfoliation. MoSe2 nanoplatelets and MoSe2 nanoplatelets/SWCNTs electrodes were manufactured using a spray-deposition method and their charge storage properties were investigated in a 1 M LiPF6/EC/DMC electrolyte in a three-electrode cell and a 3-0 V electrochemical window. MoSe2 nanoplatelets electrodes showed charge storage activity without the use of an electrically conductive additive. However, their rate performance and cycling stability was poor, which was improved by adding SWCNTs. The MoSe2 nanoplatelets/SWCNTs electrodes showed a capacity of 798 mAh gâ1 at a 0.05C rate (cycle 8), much higher than the capacity of a bulk MoSe2/carbon black electrodes of 557.0 mAh gâ1 at 0.05C (cycle 1). An improved rate performance, respect the bulk counterpart, from 0.1C (569 mAh gâ1) to 5C (153 mAh gâ1) rates, and a capacity retention of 58 % over 100 cycles at a 0.5C rate were achieved. The improved performance of the MoSe2 nanoplatelets/SWCNTs electrodes was attributed to the nanosize of the MoSe2 nanoplatelets and the combination with SWCNTs that provided mechanical stability.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 192, 20 February 2016, Pages 1-7
Journal: Electrochimica Acta - Volume 192, 20 February 2016, Pages 1-7
نویسندگان
Beatriz Mendoza-Sánchez, João Coelho, Anuj Pokle, Valeria Nicolosi,