کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6609889 | 459548 | 2015 | 30 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Branched hierarchical titanium dioxide nanoflower on carbon nanofiber with efficient scattering layer for high performance dye-sensitized solar cells
ترجمه فارسی عنوان
نانوفیلد دی اکسید تیتانیوم سلولز متعامد بر روی نانوکامپوزیت کربن با لایه پراکندگی کارآمد برای سلولهای خورشیدی حساسیت به رنگ با کارایی بالا
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
چکیده انگلیسی
A new bilayered photoanode is fabricated for dye-sensitized solar cells (DSSCs) composed of the carbon nanofiber coated by hierarchical TiO2 nanoflower (CNF-TNF) as underlayer and the urchin-like TiO2 hollow sphere (UTHS) as light-scattering layer. The CNF-TNF with a large specific surface area of 336.5Â m2Â gâ1 provides dual-functions of more dye loading and efficient charge transport, leading to the enhanced short-circuit photocurrent density of 21.40Â mA cmâ2 and prolonged electron lifetime of 189.2Â ms. The incorporated carbon nanofiber not only reduces the interfacial resistance and the charge recombination rate, but also improves the light harvesting, resulting in a high photoelectric conversion efficiency (PCE) up to 8.57% for the single-layered CNF-TNF based DSSC. In addition, by optimizing the surface morphology of TiO2 hollow sphere, we obtain the unique 3D UTHS, exhibiting strong light-scattering effect and low charge recombination due to the favorable connection among spheres provided by modified porous shell. As a consequence, an overall PCE of 9.21% is achieved for CNF-TNF+UTHS based DSSC, which is far superior to that of P25 based DSSC (5.10%). To the best of our knowledge, it is the first time that the hierarchically CNF-TNF composite is synthesized and utilized for enhanced efficiency DSSCs.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 182, 10 November 2015, Pages 257-263
Journal: Electrochimica Acta - Volume 182, 10 November 2015, Pages 257-263
نویسندگان
Peilu Zhao, Lian Wang, Deye Liu, Dan Li, Peng Sun, Fengmin Liu, Geyu Lu,