کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6613225 | 459595 | 2014 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Facile fabrication of one-dimensional mesoporous titanium dioxide composed of nanocrystals for lithium storage
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
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چکیده انگلیسی
Titanium dioxide (TiO2) has received increasing attention as promising anode for lithium ion batteries because it offers a distinct safety advantage in comparison to commercialized graphite anodes, whereas it also suffer from the drawbacks of low practical capacity and relatively low electronic conductivity. Herein, one-dimensional mesoporous anatase TiO2 composed of nanocrystals prepared by a facile procedure is reported for the first time. Such peculiar architecture and intrinsical mesoporous can effectively improve pseudocapacitance charge storage, increase contact interface between the active materials and electrolyte, and enhance the structure stability during cycling, therefore contributing to good lithium storage and excellent cycling stability. A reversible capacity of 202.9 mAhgâ1is obtained at 30 mAgâ1 after 70 cycles. More importantly, 151 mAhgâ1 can be obtained at 200 mAgâ1 even after 500 cycles.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 138, 20 August 2014, Pages 155-162
Journal: Electrochimica Acta - Volume 138, 20 August 2014, Pages 155-162
نویسندگان
Qinghua Tian, Zhengxi Zhang, Li Yang, Shin-ichi Hirano,