کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
6613849 459618 2014 8 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Preparation and characterization of proton exchange poly (ether sulfone)s membranes grafted propane sulfonic acid on pendant phenyl groups
ترجمه فارسی عنوان
آماده سازی و مشخصه غلظت پت (اتر سولفون) مبدل پروتون تبادل پروپان اسید سولفونیک در گروه آویز فنیل
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
چکیده انگلیسی
Poly(ether sulfone)s containing hexaphenyl (PHP) was prepared by 1,2-bis(4-hydroxyphenyl)-3,4,5,6-tetraphenylbenzene, 4,4-hydroxyphenylsulfone, and 4,4-fluorophenylsulfone, followed bromination on phenyl groups to produce brominated PHP (Br-PHP). Grafted sulfonated poly(ether sulfone)s containing hexaphenyl (GSPHP) were prepared from Br-PHP and 3-bromopropane sulfonic acid with potassium salt and copper powder. The salt form was converted to free acid using 1 M sulfuric acid solution. All these membranes were cast from dimethylacetamide (DMAc). The structural properties of the synthesized polymers were investigated by 1H-NMR spectroscopy. The membranes were studied with regard to ion exchange capacity (IEC), water uptake, Fenton test, and proton conductivity. These grafted polymer membranes were compared with normal sulfonated poly(ether sulfone)s and Nafion
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 118, 1 February 2014, Pages 18-25
نویسندگان
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