کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6615073 | 459616 | 2013 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Hybrid supercapacitor materials from poly(3,4-ethylenedioxythiophene) conformally coated aligned carbon nanotubes
ترجمه فارسی عنوان
مواد ابررسانای ترکیبی از پلی (3،4-اتیلن اکسید تیتیوفن) نانولوله های کربنی تطبیقی
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کلمات کلیدی
نانولوله کربنی همسان ضخامت پوشش مناسب پلیمر هدایت کننده ابرخازنها،
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
چکیده انگلیسی
Conducting polymer poly(3,4-ethylenedioxythiophene) (PEDOT) conformally coated aligned carbon nanotubes (PEDOT/A-CNTs) were developed and investigated as the active material for supercapacitor electrode applications and the results were compared to those of non-coated CNTs as well as that of PEDOT coated randomly packed CNTs. The electrochemical performance of the electrodes was evaluated by cyclic voltammetry (CV), galvanostatic charge/discharge, and electrochemical impedance spectroscopy (EIS). The results revealed that the PEDOT conformally coated and densified (5% volume fraction, Vf) A-CNTs exhibit a specific volumetric capacitance of 84.0Â F/cm3, much higher compared to the non-coated and non-densified A-CNTs (1%Â Vf) that had a specific capacitance of only 3.9Â F/cm3. Ion insertion/de-insertion processes in the PEODT coating layers are observed in impedance spectra for the PEDOT-coated A-CNT electrodes at rates that are not limiting to cell performance relative to ion transport through the channels formed by the PEDOT/A-CNTs. Specific energy and power densities of 11.8Â Wh/l and 34.0Â kW/l, respectively, were obtained for these nano-tailored electrodes, with high capacitance retention compared with those of PEDOT coated random CNTs.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 112, 1 December 2013, Pages 522-528
Journal: Electrochimica Acta - Volume 112, 1 December 2013, Pages 522-528
نویسندگان
Mehdi Ghaffari, Suppanat Kosolwattana, Yue Zhou, Noa Lachman, Minren Lin, Dhiman Bhattacharya, Karen K. Gleason, Brian L. Wardle, Q.M. Zhang,