کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6616044 | 459630 | 2013 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Carbon-supported Pd-Cr electrocatalysts for the electrooxidation of formic acid that demonstrate high activity and stability
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
In this paper, we first report that Pd-Cr alloy can be used as a catalyst for the anodic oxidation of formic acid (FAO). A series of carbon supported Pd-Cr alloy (Pd-Cr/C) catalysts with different Pd-Cr atom ratios was prepared with chemical reduction method. The PdxCr1âx/C catalysts (0.1 â¤Â x â¤Â 0.4) showed better performance toward the anodic oxidation of formic acid than Pd/C and Pt/C. Among them, Pd0.8Cr0.2/C (Pd/Cr = 8:2, atomic ratio) exhibits the highest catalytic activity. Compared with Pd/C catalyst, the potential of anodic peak of formic acid at the Pd0.8Cr0.2/C catalyst electrode shifted toward negative value by 50 mV. Pd0.8Cr0.2/C also exhibits high stability, suggesting that Pd0.8Cr0.2/C is a good candidate for the formic acid fuel cell. The characteristics of Pd0.8Cr0.2/C were correlated using X-ray diffraction analysis, X-ray photoelectron spectroscopy, transmission electron microscopy, and electrochemical measurements.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 109, 30 October 2013, Pages 201-206
Journal: Electrochimica Acta - Volume 109, 30 October 2013, Pages 201-206
نویسندگان
Wenjuan Wen, Chunyou Li, Wenpeng Li, Yan Tian,