کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6617294 | 459629 | 2013 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Characterization of a model solid electrolyte interphase/carbon interface by combined in situ Raman/Fourier transform infrared microscopy
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A novel in situ microscopic approach combining Raman and infrared micro-spectroscopy for the study of interfacial reactions and the spectral characterization of the local structure at the same spot on the surface of electrodes was developed. As a proof of concept, the impact of vinylene carbonate and ethylene sulfite additives on SEI film formation was studied, using highly reflective glassy carbon (GC) as a model system for graphite-based anodes. By micro-FTIR spectroscopy, solvation-desolvation interfacial phenomena were detected, while the carbonaceous material was characterized by micro-Raman spectroscopy at the same spot on the GC surface.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Electrochimica Acta - Volume 106, 1 September 2013, Pages 506-515
Journal: Electrochimica Acta - Volume 106, 1 September 2013, Pages 506-515
نویسندگان
S. Pérez-Villar, P. Lanz, H. Schneider, P. Novák,