کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6656486 | 1425374 | 2018 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Preparation of synthetic graphite from bituminous coal as anode materials for high performance lithium-ion batteries
ترجمه فارسی عنوان
آماده سازی گرافیت مصنوعی از ذغال سنگ بتمن به عنوان مواد آند برای باتری های لیتیوم یون با کارایی بالا
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کلمات کلیدی
گرافیت مصنوعی، ذغال سنگ بتمنس، درمان گرافیتی مواد آنود، باتری های لیتیوم یون،
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
چکیده انگلیسی
An earth-abundant and low cost bituminous coal was used as precursor to prepare synthetic graphite materials through preliminary carbonization coupled with further high temperature graphitization treatment at 2000-2800 °C. The microstructure characteristics of the obtained synthetic graphite materials were characterized by means of X-ray diffraction, scanning electron microscope, transmission electron microscope, Raman spectroscopy and nitrogen adsorption-desorption. The results show that the microstructures of synthetic graphite materials are strongly dependent on the graphitization temperature. The synthetic graphite graphitized at 2800 °C has perfect ordered layered structure with high graphitization degree and relatively large surface area with well-developed mesopores, which offers a favorable pathway for the electrochemical intercalation-deintercalation of lithium ions in carbon matrix. Such synthetic graphite applied as anode materials for lithium-ion batteries presents a maximum reversible capacity of 310.3 mAh·gâ 1 at current rate of 0.1C and still remains as high as 143.9 mAh·gâ 1 at current rate of 5C. Moreover, the synthetic graphite also exhibits superior rate capability and outstanding cycling performance with over 95.3% initial capacity retention after 100 cycles. This study demonstrates a promising feasibility for large-scale production of synthetic graphite materials from bituminous coal for high performance lithium-ion batteries.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Fuel Processing Technology - Volume 172, April 2018, Pages 162-171
Journal: Fuel Processing Technology - Volume 172, April 2018, Pages 162-171
نویسندگان
Baolin Xing, Chuantao Zhang, Yijun Cao, Guangxu Huang, Quanrun Liu, Chuanxiang Zhang, Zhengfei Chen, Guiyun Yi, Lunjian Chen, Jianglong Yu,