کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6656727 | 461661 | 2016 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
A highly active solid acid for specifically catalyzing di(1-naphthyl)methane hydrocracking in cyclohexane
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
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چکیده انگلیسی
A highly active solid acid was prepared by impregnating trifluoromethanesulfonic acid (TFMSA) onto mesostructured zirconium oxide (MSZO). Di(1-naphthyl)methane (DNM) was used as a coal-related model compound to evaluate the catalytic activity of TFMSA/MSZO for cleaving strong C-C bridged bonds in coals. As a result, TFMSA/MSZO was found to be effective for hydrocracking DNM to naphthalene and 1-methylnaphthalene in cyclohexane without adding gaseous hydrogen and MSZO is a much better support than activated carbon, γ-Al2O3, and ZSM-5 zeolite. Based on the kinetic investigation, the apparent activation energy of DNM hydrocracking over TFMSA/MSZO is only 32.0 kJ·molâ1, which is much lower than the dissociation energy (355.6 kJ·molâ1) of the bridged bond in DNM. The proton transfer directly from TFMSA/MSZO and/or via cyclohexane dehydrogenation over TFMSA/MSZO to the ipso-position of DNM could be the crucial step for DNM hydrocracking.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Fuel Processing Technology - Volume 142, February 2016, Pages 258-263
Journal: Fuel Processing Technology - Volume 142, February 2016, Pages 258-263
نویسندگان
Mei-Xia Zhao, Xian-Yong Wei, Meng Qu, Zhan-Ku Li, Jing Liu, Jiao Kong, Dong-Dong Zhang, Hong-Lei Yan, Zhi-Min Zong,