کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6659635 | 1426188 | 2018 | 19 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Solubilities of sulfuryl fluoride in propylene carbonate, tributyl phosphate and N-methylpyrrolidone
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
مهندسی شیمی (عمومی)
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چکیده انگلیسی
The solubilities of sulfuryl fluoride (SO2F2) in propylene carbonate (PC), tributyl phosphate (TBP) and N-methylpyrrolidone (NMP) was measured by isochoric saturation method at the pressure of up to 600â¯kPa and temperatures ranging from (293.15 to 313.15)â¯K. Results showed that SO2F2 solubility increased with increasing pressure and decreased with increasing temperature in the three solvents, and the dissolution of SO2F2 in the solvents was a physical process. Moreover, Henry's law constants and thermodynamic properties such as standard Gibbs free energy, enthalpy, and entropy changes of SO2F2 solvation were further calculated according to the experimental solubility data. The solubility of SO2F2 in these three solvents followed the order of TBPâ¯>â¯PCâ¯>â¯NMP. The results illustrated that TBP possessed the potentiality to capture SO2F2 among the present absorbents due to the relatively large solubility and low absorption enthalpy for SO2F2.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: The Journal of Chemical Thermodynamics - Volume 125, October 2018, Pages 11-16
Journal: The Journal of Chemical Thermodynamics - Volume 125, October 2018, Pages 11-16
نویسندگان
Xiaojiang Liang, Shilin Ye, Qinglong Xie, Meizhen Lu, Fan Xia, Yong Nie, Zhiyan Pan, Jianbing Ji,