Hydrolysis behavior of regenerated celluloses with different degree of polymerization under microwave radiation

• Degree of polymerization (DP) plays a crucial role on hydrolysis of cellulose.
• Low DP can alleviate the recrystallization of cellulose then promote hydrolysis.
• The hydrolytic efficiency is significantly improved when the DP is lower than 51.

This work studied the hydrolysis behavior of regenerated celluloses (RCs) with different degree of polymerization (DP) by using the catalyst of dilute acid under microwave radiation. Results showed that the DP had a considerable influence on hydrolysis of cellulose. The reactivity of RCs was significantly improved when DP was lower than 51. The highest sugar yield of 59.2% was achieved from RC with lowest DP of 23 at 160 °C for 15 min. But the lowest yield of 32.6% was obtained when RC with highest DP of 132 was used. Recrystallization of cellulose was found to hinder the further hydrolysis particularly with the high DP. The effect of recrystallization can be reduced by the decrease of DP of RCs. This research demonstrates that the DP of RCs plays a crucial role on hydrolysis and it provides a preliminary guide based on DP to find a suitable pretreatment method for cellulose hydrolysis.

The reactivity of regenerated cellulose is significantly enhanced when the degree of polymerization of cellulose is lower than 51.Figure optionsDownload as PowerPoint slide