Ultrasonic-assisted production of biodiesel from transesterification of palm oil over ostrich eggshell-derived CaO catalysts

• Waste ostrich eggshell-derived CaO catalyst was synthesized for the first time.
• The biodiesel yield can be remarkably enhanced under ultrasonic conditions.
• Maximum biodiesel yield (92.7%) was achieved in the ultrasonic system.
• This CaO(OE) could exhibit a desirable recyclability.

In this study, waste ostrich eggshell-derived calcium oxide (denoted as CaO(OE)) particles were synthesized and explored as cost-effective catalysts for the ultrasonic-assisted transesterification of palm oil. The physicochemical properties of the resultant catalysts were characterized by XRD, N2 adsorption, XRF and Hammett indicator, while the catalytic activity was evaluated through transesterification of palm oil with methanol under ultrasonic conditions. More specifically, the CaO(OE) showed comparable catalytic activity to the one derived from commercial calcium carbonate (denoted as CaO(Lab)). Moreover, under ultrasonic conditions, the catalytic activity of CaO(OE) could be enhanced significantly. The maximum yield of fatty acid methyl esters could reach 92.7% under the optimal condition of reaction time of 60 min with ultrasonic power of 60% (120 W), methanol-to-oil ratio of 9:1, and catalyst loading of 8 wt.%. The results indicated that the CaO(OE) catalysts showed good catalytic performance and reusability, and may potentially reduce the cost of biodiesel production.

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