کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
72527 49023 2015 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Microwave synthesis of AFI-type aluminophosphate molecular sieve under solvent-free conditions
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Microwave synthesis of AFI-type aluminophosphate molecular sieve under solvent-free conditions
چکیده انگلیسی


• AlPO4-5 was synthesized by microwave irradiation under solvent-free conditions.
• AFI molecular sieves have hierarchical micro- and meso-porous structure.
• Pretreated activated carbon was used as the reaction medium for AFI synthesis.

AlPO4-5 aluminophosphate molecular sieve with AFI topology has been successfully synthesized by microwave irradiation under solvent-free conditions. The key influential factors controlling the crystallization of AFI structure were thoroughly investigated. The optimum synthetic conditions of this material are as follows: the initial composition is 1.0Al2O3: 3.0P2O5: 2.0HF: 8.0TEABr(tetraethylammonium bromide): 125C, aluminum isopropoxide is the best aluminum source, and activated carbon needs to be pretreated before used as the reaction medium and hard template. The resultant AlPO4-5 molecular sieves were characterized by X-ray diffraction (XRD), N2 physisorption, scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The results reveal that the obtained samples exhibit hierarchically porous characteristic.

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ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Microporous and Mesoporous Materials - Volume 213, 1 September 2015, Pages 192–196
نویسندگان
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