کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
72536 | 49024 | 2015 | 4 صفحه PDF | دانلود رایگان |
• Supermicroporous silicas (Dpore = 0.7–2.0 nm) were synthesized by solvent-free method.
• The effect of micropore size for dynamic adsorption efficiency was investigated.
• The dynamic adsorption efficiency was highly enhanced in the pores smaller than 1 nm.
The dynamic adsorption of toluene was investigated using supermicroporous silicas (SMPSs) synthesized through a solvent-free route by using tetraethoxysilane and conventional alkyltrimethylammonium halides as a structure-directing agent. The adsorption capacity of SMPSs depended on their pore diameters, which were precisely tuned in a range from 0.7 to 2.0 nm at single-angstrom intervals. The micropore filling of the molecule that is highly enhanced with micropores smaller than 1 nm improves the dynamic adsorption performance.
Figure optionsDownload as PowerPoint slide
Journal: Microporous and Mesoporous Materials - Volume 214, 15 September 2015, Pages 41–44