کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
73710 49068 2013 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
High xenon/krypton selectivity in a metal-organic framework with small pores and strong adsorption sites
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
High xenon/krypton selectivity in a metal-organic framework with small pores and strong adsorption sites
چکیده انگلیسی

Separation of Xe/Kr mixtures was studied in two copper-paddlewheel metal-organic framework materials, MOF-505 and HKUST-1. For MOF-505, which has small pores with strong adsorption sites, high Xe/Kr selectivities (9–10) are obtained from breakthrough measurements and grand canonical Monte Carlo (GCMC) simulations. The consistent results from both techniques suggest that MOF-505 is a promising candidate for Xe/Kr separation. For HKUST-1, which has small octahedral pores, only modest Xe/Kr selectivities (4.5) are observed from breakthrough measurements, although the GCMC simulations predicted unusually high selectivities at low loadings.

Figure optionsDownload as PowerPoint slideHighlights
► MOF-505 shows high Xe/Kr selectivity from both experiments and simulations.
► The experimental selectivities for MOF-505 (9–10) are among the highest ones reported.
► HKUST-1 shows modest experimental selectivity in breakthrough measurements.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Microporous and Mesoporous Materials - Volume 169, 15 March 2013, Pages 176–179
نویسندگان
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