کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
73793 | 49071 | 2012 | 6 صفحه PDF | دانلود رایگان |
Cu–BTC metal organic framework, HKUST-1 was synthesized by solvothermal method and characterized using surface area analyser, scanning electron microscope, powder X-ray diffractometer, Fourier transform infrared spectrophotometer and thermo gravimetric analyser. HKUST-1 thus produced and characterized, was studied for the degradation of sulfur mustard (HD) and its surrogate 2-chloroethyl ethyl sulfide (CEES) using gas chromatograph coupled with flame ionization detector. From the reaction kinetics it was observed that the CEES degraded faster relative to HD. The rate constant and half life were found to be 0.02 min−1, 34.65 min and 0.043 min−1, 16.11 min for HD and CEES respectively. Degradation products were analyzed by gas chromatograph coupled with mass spectrometer. At the same time reusability of the HKUST-1 has also been explored.
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► Synthesis of Cu–BTC metal organic framework.
► Degradation of sulfur mustard and its simulant 2-chloroethyl ethyl sulfide.
► Reaction pathway for degradation of sulfur mustard and 2-chloroethyl ethyl sulfide.
Journal: Microporous and Mesoporous Materials - Volume 162, 1 November 2012, Pages 207–212