کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
74643 49096 2011 7 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Synthesis of nanosized mesoporous Co–Al spinel and its application as solid base catalyst
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی کاتالیزور
پیش نمایش صفحه اول مقاله
Synthesis of nanosized mesoporous Co–Al spinel and its application as solid base catalyst
چکیده انگلیسی

A novel mesoporous Co–Al spinel catalyst with high surface area and suitable basicity was prepared by the thermal decomposition of Co–Al hydrotalcite-like compound. The properties of the solid base catalyst were characterized by XRD, FTIR, TEM, nitrogen sorption and CO2-TPD. The formation mechanism of the mesopores and the Co–Al spinel structure was also investigated by TG/DTA and mass-spectrometer, respectively. This is due to the partial oxidation of Co2+ ions and the dehydration of the interface OH groups in precursor. The formed Co3+ ions collapsed into the interlayer space, coordinated with the adjacent oxygen atoms (tetrahedral or octahedral), worked as pillars between layers and made the interlayer space to be almost opened (mesopores formed). The partial oxidation of Co2+ ions plays a critical role in the phase transformation and the formation of mesopores. The as-obtained mesoporous Co–Al spinel-type solid base catalyst was first used in the aldol condensation of furfural with acetone and the self-condensation of acetone and found that it had good activity and excellent selectivity in both reactions. The stability studies showed that the catalyst can be completely regenerated easily by calcination.

A novel mesoporous Co–Al spinel type solid base catalyst with high surface area was prepared, which was used for the aldol condensation of furfural with acetone and the self-condensation of acetone with high activity and easy regeneration.Figure optionsDownload as PowerPoint slideResearch highlights
► A novel mesoporous Co–Al spinel-type solid base catalyst was prepared.
► The partial oxidation of Co2+ and dehydration of interface OH play the role.
► This kind of solid base catalyst was used in Aldol condensation with good activity.
► The catalytic activity can be completely regenerated easily by calcination.

ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Microporous and Mesoporous Materials - Volume 142, Issue 1, June 2011, Pages 251–257
نویسندگان
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