کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
75241 | 49112 | 2008 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Diphosphine probe molecules and solid-state NMR investigations of proximity between acidic sites in zeolite HY
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The proximity between acidic sites in zeolite HY with different n(Si)/n(Al) ratios was investigated by applying 31P MAS NMR and diphosphine probe molecules, with two phosphorous atoms that can bind to two nearby acidic sites. By careful analyses of NMR spectra of samples with appropriate loading levels, the fractions of species which are connected to two/one/zero acidic sites were determined. The results presented suggest that there are no acidic clusters in the high Si/Al-content zeolite HY samples investigated in this study.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Microporous and Mesoporous Materials - Volume 116, Issues 1–3, December 2008, Pages 277–283
Journal: Microporous and Mesoporous Materials - Volume 116, Issues 1–3, December 2008, Pages 277–283
نویسندگان
Luming Peng, Clare P. Grey,