کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
7690232 1495907 2014 14 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Theory of sampling (TOS) versus measurement uncertainty (MU) - A call for integration
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی آنالیزی یا شیمی تجزیه
پیش نمایش صفحه اول مقاله
Theory of sampling (TOS) versus measurement uncertainty (MU) - A call for integration
چکیده انگلیسی
We assess current approaches to measurement uncertainty (MU) with respect to the complete ensemble of sources affecting the measurement process, in particular the extent to which sampling errors as set out in the Theory of Sampling (TOS) are appropriately considered in the GUM and EURACHEM/CITAC guides. All pre-analysis sampling steps play an important, often dominant role in the total uncertainty budget, thereby critically affecting the validity of MU estimates, but most of these contributions are not included in the current MU framework. The TOS constitutes the only complete theoretical platform for dealing appropriately with the entire pathway from field sample to test portion. We here propose a way to reconcile the often strongly felt differences between MU and TOS. There is no need to debate terminology, as both TOS and MU can be left with their current usages.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: TrAC Trends in Analytical Chemistry - Volume 57, May 2014, Pages 93-106
نویسندگان
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